Metal-Organic Framework-Based Materials for Aqueous Zinc-Ion Batteries: Energy Storage Mechanism and Function.

Aqueous rechargeable zinc-ion batteries (ZIBs) featuring competitive performance, low cost and high safety hold great promise for applications in grid-scale energy storage and portable electronic devices. Metal-organic frameworks (MOFs), relying on their large framework structure and abundant active sites, have been identified as promising materials in ZIBs. This review comprehensively presents the current development of MOF-based materials including MOFs and their derivatives in ZIBs, which begins with Zn storage mechanism of MOFs, followed by introduction of various types of MOF-based cathode materials (PB and PBA, Mn-based MOF, V-based MOF, conductive MOF and their derivatives), and the regulation approaches for Zn deposition behavior. The key factors and optimization strategies of MOF-based materials that affect ZIBs performance are emphasized and discussed. Finally, the challenges and further research directions of MOF-based materials for advanced zinc-ion batteries are provided.