Effects of the novel catalyst Ni-S 2 O 8 2- -K 2 O/TiO 2 on efficient lignin depolymerization.

To improve the utilization of lignin, much effort has been devoted to lignin depolymerization with the aim to decrease waste and enhance profitability. Here, a dual property (acid and base) catalyst, namely S 2 O 8 2- -K 2 O/TiO 2 , was carefully researched. Upon loading S 2 O 8 2- and K 2 O onto TiO 2 , acid and base sites emerged, and S 2 O 8 2- and K 2 O mutually enhanced the acid and base strengths of the catalyst enormously; this indeed facilitated lignin depolymerization. Under appropriate conditions, the yields of liquid product, petroleum ether soluble (PE-soluble) product and total monomer products were 83.76%, 50.4% and 28.96%, respectively. The constituents of the PE-soluble fraction, which are mainly monomers and dimers, can be used as liquid fuels or additives. In addition, after the catalyst was modified by Ni, better results were obtained. Surprisingly, it was found that the Ni enhanced not only the hydrogenation capacity but also the acidity. The highest high heating value (HHV) of the liquid product (33.6 MJ kg -1 ) was obtained, and the yield of PE-soluble product increased from 50.4 to 56.4%. The product can be utilized as a fuel additive or be converted to bio-fuel. This catalysis system has significant potential in the conversion of lignin to bio-fuel.