Contact-Electro-Catalysis-Assisted Separation via a Dancing PTFE Membrane for Fouling Control.

Advanced oxidization processes (AOPs) offer promising solutions for addressing the fouling issues in membrane separation systems. However, the high energy requirements for electrical or light power in the AOPs can be a drawback. In this study, we present a contact-electro-catalysis (CEC)-based approach for controlling membrane fouling, which is stimulated by mild ultrasonic irradiation. During this process, electrons are transferred between a dancing polytetrafluoroethylene membrane and water or oxygen molecules, resulting in the formation of free radicals • OH and • O 2 - . These free radicals are capable of degrading or inactivating foulants, eliminating the need for additional chemical cleaners, secondary waste disposal, or external stimuli. Furthermore, the time-dependent voltage spikes/oscillations (peak, +7.8/-8.2 V) generate a nonuniform electric field that drives dielectrophoresis, effectively keeping contaminants away from the membrane surface and further enhancing the antifouling performance of the dancing membrane. Therefore, the CEC-assisted membrane separation system offers a green and effective strategy for controlling membrane fouling through mild mechanical stimulation.