(111)-Dominated Perovskite Films by Antisolvent Engineering.

Fabricating perovskite films with a dominant crystal orientation is an effective path to realize quasi-single crystal perovskite film, which can eliminate the fluctuation of the electrical properties in films arising from grain-to-grain variations, and improve the performance of perovskite solar cells (PSCs). Perovskite (FAPbI 3 ) films based on one-step antisolvent methods usually suffer from chaotic orientations due to the inevitable intermediate phase conversion from intermediates of PbI 2 •DMSO, FA 2 Pb 3 I 8 •4DMSO and δ-FAPbI 3 to α-FAPbI 3 . Here we report a high-quality perovskite film with (111) preferred orientation ((111)-α-FAPbI 3 ) using a short-chain isomeric alcohol antisolvent, isopropanol (IPA) or isobutanol (IBA). The interaction between IPA and PbI 2 leads to a corner sharing structure instead of an edge-sharing PbI 2 octahedron, sidestepping the formation of these intermediates. With the volatilization of IPA, FA + can replace IPA in situ to form α-FAPbI 3 along the (111) direction. Compared to randomly-orientated perovskites, the dominantly (111) orientated perovskite ((111)-perovskite) exhibits improved carrier mobility, uniform surface potential, suppressed film defects and enhanced photostability. PSCs based on the (111)-perovskite films show 22% power conversion efficiency and excellent stability, which remains unchanged after 600 h continuous working at maximum power point, and 95% after 2000 h of storage in atmosphere environment. This article is protected by copyright. All rights reserved.