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SnO 2 QDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor.

Molahalli VandanaAman SharmaApoorva ShettyGurumurthy Hegde
Published in: Biosensors (2022)
In this present work, we demonstrate an efficient electrochemical sensor for the detection of hydrogen peroxide (H 2 O 2 ) using a glassy carbon electrode (GCE) modified with a ternary nanocomposite of tin oxide QDs/GO/PPy (SGP2). An in situ chemical oxidative polymerization method was used to create the SGP2 nanocomposite. FTIR, XRD, HR TEM, CV, DPV, and impedance analysis were used to characterize the nanocomposite. The SGP2 nanocomposite modified GCE can be used to create an effective H 2 O 2 electrochemical sensor with high sensitivity and a low detection limit (LOD). With SGP2 modified GCE, the electrochemical detection test for H 2 O 2 was carried out using cyclic voltammetry (CV) and amperometric methods. The SGP2 modified GCE shows improved sensing capabilities, resulting in considerable sensitivity of 11.69 µA mM cm -2 and a very low limit of detection (LOD) of 0.758 µM for a broad linear range of H 2 O 2 concentration from 0.1 mM to 0.8 mM with a correlation coefficient R 2 = 0.9886. Additionally, the performance of the SGP2-modified GCE electrode is on par with or nonetheless superior to that of the other functional materials that have been reported for H 2 O 2 . As a result, our findings suggest that combining conductive polymer with metal oxide may be a useful method for producing sophisticated and affordable electrochemical sensors.
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