Effect of logarithmic perturbations in Ohmic like spectral densities in dynamics of Electronic Excitation using variational polaron transformation approach.

Electronic excitation energy transfer is a ubiquitous process that has generated prime research interest since its discovery. Recently developed variational polaron transformation-based second-order master equation is capable of interpolating between Forster and Redeld limits with exceptional accuracy. Forms of spectral density functions studied so far through the variational approach provide theoretical support for various experiments. Recently introduced Ohmic like spectral density function that can account for logarithmic perturbations provides generality and exposition to a unique and practical set of environments. In this paper, we exploit the energy transfer dynamics of a two-level system attached to an Ohmic like spectral density function with logarithmic perturbations using a variational polaron transformed master equation. Our results demonstrate that even for a relatively large bath coupling strength, quantum coherence effects can be increased by introducing logarithmic perturbations of the order of one and two in super-Ohmic environments. Moreover, for particular values of the Ohmicity parameter, the effect of logarithmic perturbations is observed to be insignificant for the overall dynamics. In regard to Ohmic environments, as logarithmic perturbations increase, damping characteristics of the coherent transient dynamics also increase in general. It is also shown that having logarithmic perturbations of the order of one in an Ohmic environment can result in a less efficient energy transfer for relatively larger system bath coupling strengths.