V2Se: a novel antifluorite-type cubic phase with a metal-metal bonding.
Gihun RyuDinh Loc DuongPublished in: Dalton transactions (Cambridge, England : 2003) (2019)
A new antifluorite-type (Li2O-type) cubic compound, V2Se, has been synthesized for the first time by changing the amount of selenium in chemical vapor transport. The vanadium-based cubic phase studied here reveals a metal-metal bonding feature in the electronic band structure. This compound is the first example of an antifluorite-type cubic structure in a V-Se system.
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