Oxidative Intramolecular 1,2-Amino-Oxygenation of Alkynes under AuI /AuIII Catalysis: Discovery of a Pyridinium-Oxazole Dyad as an Ionic Fluorophore.

Aslam C ShaikhDnyanesh S RanadePattuparambil R RajamohananPrasad P Kulkarni Nitin T Patil

Published in: Angewandte Chemie (International ed. in English) (2016)

Oxidative intramolecular 1,2-amino-oxygenation reactions, combining gold(I)/gold(III) catalysis, is reported. The reaction provides efficient access to a structurally unique ionic pyridinium-oxazole dyad with tunable emission wavelengths. The application of these fluorophores as potential biomarkers has been investigated.

Keyphrases

energy transfer
solid state
ionic liquid
blood flow
small molecule
silver nanoparticles
visible light
high throughput
fluorescent probe
atomic force microscopy
mass spectrometry
high resolution