Fabricating defect-rich metal-organic frameworks via mixed linker-induced crystal transformation.

Yue XiaoLu HanZhuxiu Zhang Lifang TianZhuxiu ZhangLixiong ZhangDong YangXu Qiao

Published in: Chemical communications (Cambridge, England) (2022)

Defect-rich hcp UiO-66-NO 2 was synthesized via mixed linker-induced crystal transformation from fcu UiO-66-NO 2 /NH 2 . The defect concentration and porosity of hcp UiO-66-NO 2 can be fine-tuned by varying the BDC-NH 2 /BDC-NO 2 ratio, which in turn endowed hcp UiO-66-NO 2 with superior catalytic performance in the ring-opening reaction of epoxides with alcohols.

Keyphrases

metal organic framework
high glucose
diabetic rats
oxidative stress
fluorescent probe
single molecule
soft tissue
crystal structure
oxide nanoparticles