Enhanced Electrochemical Performance of a Ti-Cr-Doped LiMn 1.5 Ni 0.5 O 4 Cathode Material for Lithium-Ion Batteries.

Ti, Cr dual-element-doped LiMn 1.5 Ni 0.5 O 4 (LNMO) cathode materials (LTNMCO) were synthesized by a simple high-temperature solid-phase method. The obtained LTNMCO shows the standard structure of the Fd 3 ®m space group, and the Ti and Cr doped ions may replace the Ni and Mn sites in LNMO, respectively. The effect of Ti-Cr doping and single-element doping on the structure of LNMO was studied by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) characteristics. The LTNMCO exhibited excellent electrochemical properties with a specific capacity of 135.1 mAh·g -1 for the first discharge cycle and a capacity retention rate of 88.47% at 1C after 300 cycles. The LTNMCO also has high rate performance with a discharge capacity of 125.4 mAh·g -1 at a 10C rate, 93.55% of that at 0.1C. In addition, the CIV and EIS results show that the LTNMCO showed the lowest charge transfer resistance and the highest diffusion coefficient of lithium ions. The enhanced electrochemical properties may be due to a more stable structure and an optimized Mn 3+ content in LTNMCO through TiCr doping.