Polypyrrole/tannin biobased nanocomposite with enhanced electrochemical and physical properties.
Mahnaz M AbdiNur Farhana Waheeda Mohd AzliHong Ngee LimParidah Md TahirGholamreza KarimiYeoh Beng HoongMohammad KhorramPublished in: RSC advances (2018)
In this research, tannin (TA) extracted from Acacia mangium and a cationic surfactant, cetyltrimethylammonium bromide (CTAB), were used to modify and enhance the physical and electrochemical properties of a polypyrrole (PPy) composite. Brunauer-Emmett-Teller (BET) analysis presented a higher degree of surface area and porosity for the PPy/TA/CTAB nanocomposite. A highly porous and rod like structure with a lumpy surface was observed for PPy/TA prepared in the presence of CTAB by Field Emission Scanning Electron Microscopy (FESEM) and Transmission Electron Microscopy (TEM). Cyclic voltammograms of the modified SPE electrode using PPy/TA/CTAB displayed an enhanced current response compared to the electrode modified with only PPy or PPy/TA. Electrochemical Impedance Spectroscopy (EIS) exhibited a lower value of charge transfer resistance ( R ct ) and higher electron transfer for the modified electrode, making the nanocomposite a promising candidate for biosensor application.
Keyphrases
- electron microscopy
- reduced graphene oxide
- gold nanoparticles
- molecularly imprinted
- carbon nanotubes
- solid phase extraction
- electron transfer
- label free
- quantum dots
- physical activity
- solid state
- ionic liquid
- mental health
- computed tomography
- highly efficient
- dual energy
- high resolution
- single molecule
- magnetic resonance imaging
- sensitive detection
- image quality
- positron emission tomography
- contrast enhanced
- simultaneous determination