An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties.

Yuliia P Petrenko Karolina Piasta Dmytro M KhomenkoRoman O DoroshchukSergiu ShovaGhénadie NovitchiYuliya Toporivska Elzbieta Gumienna-Kontecka Luísa M D R S MartinsRostyslav D Lampeka

Published in: RSC advances (2021)

Two new copper(ii) complexes [Cu 2 (L) 2 (OAc) 2 (H 2 O) 2 ] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL 2 ] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling.

Keyphrases

molecularly imprinted
oxide nanoparticles
hydrogen peroxide
room temperature
nitric oxide
mass spectrometry
high resolution
ionic liquid