Dissolution behavior of precious metals and selective palladium leaching from spent automotive catalysts by trihalide ionic liquids.

The dissolution behavior of the precious metals gold, platinum, rhodium and palladium in the trihexyl(tetradecyl)phosphonium trihalide ionic liquids [P 66614 ][Cl 3 ], [P 66614 ][Br 3 ], [P 66614 ][IBr 2 ] and [P 66614 ][I 3 ] was investigated. The highest dissolution rates were observed for the trichloride ionic liquid [P 66614 ][Cl 3 ] and this system was investigated in more detail. The effects of the trichloride concentration in the ionic liquid and temperature were studied, reaching higher leaching rates at higher trichloride conversions and increased temperatures. The stability of the trichloride anion at these elevated temperatures was studied by Raman spectroscopy. It was found that the trichloride anion decomposed during leaching at higher temperatures, showing the requirement to store these reactive compounds in sealed and cool environments, shielded from light. The optimal leaching conditions were applied for the recovery of palladium from ceramic monolith powder, obtained from end-of-life automotive catalysts. The catalyst powder was contacted with the ionic liquid [P 66614 ][Cl 3 ] and the metal concentrations in the ionic liquid were monitored. The trihalide ionic liquid allowed a more selective leaching of palladium compared to other metals present at very high concentrations in the monolith structure, like magnesium. The relative ratio of palladium over magnesium increased by two orders of magnitude compared to the original catalyst composition. The effect of the contact time between the catalyst powder and the ionic liquid on the metal concentrations in the leachate was investigated, but no significant improvement in the selectivity was observed.