Trinuclear Cobalt(II) Triple Helicate with a Multidentate Bithiazolebis(oxamate) Ligand as a Supramolecular Nanomagnet.
Lucas H G KalinkeRenato RabeloAna K ValdoFelipe Terra MartinsNicolás MolinerJesus Ferrando SoriaMiguel JulveFrancesc LloretJoan CanoDanielle CangussuPublished in: Inorganic chemistry (2022)
The cobalt(II)-mediated self-assembly of the potentially tris(chelating) N , N '-2,2'-(4,4'-bithiazole)bis(oxamate) (dabtzox) ligand gives a new metal-organic supramolecular nanomagnet of formula K 6 Co 3 (dabtzox) 3 ·8H 2 O·MeOH ( 1 ) featuring a unique linear triple-stranded trinuclear structure of the helicate type.