A covalently linked nickel(II) porphyrin-ruthenium(II) tris(bipyridyl) dyad for efficient photocatalytic water oxidation.

Emmanouil NikoloudakisAjyal Z AlsalehGeorgios Chararalambidis Athanassios G Coutsolelos Francis D'Souza

Published in: Chemical communications (Cambridge, England) (2022)

Visible-light-induced oxidation of water to dioxygen, catalyzed by a newly synthesized NiP-Ru dyad consisting of a ruthenium tris(bipyridyl), [Ru(bpy) 3 ] 2+ as a photosensitizer, and a low-cost nickel porphyrin, NiP as a water oxidation catalyst is reported.

Keyphrases

photodynamic therapy
metal organic framework
low cost
visible light
reduced graphene oxide
electron transfer
energy transfer
hydrogen peroxide
room temperature
highly efficient
oxide nanoparticles
gold nanoparticles
nitric oxide
carbon nanotubes