Effect ofα-substitute group on the chirality of monocarboxylic acid stabilized CdSe nanocrystals.

The effect ofα-substitute groups at the asymmetric carbon of chiral monocarboxylic acid ligand, on the chirality of CdSe nanocrystals (NCs) was studied. When the substitution groups have strong electron-withdrawing capability, the CdSe NCs displayed an enhanced chirality where theg-factors were comparable to those with dicarboxylic chiral ligands. In addition, adding ethanol was demonstrated as an effective way to stabilize NCs, however, completely oppositeg-factor evolution behavior was found for NCs with differentα-substituted ligands. Specifically, theg-factor has increased/decreased with strong/weak electron-withdrawingα-substitute groups probably due to the different intermolecular hydrogen bonding between carboxylic acids and ethanol.