Two Unprecedented Reactions of Nitrosyl Triflate: NO + -Induced Cationic Cascade Cyclization and C═C Oxidative Cleavage.

Published in: Organic letters (2023)

Nitrosyl triflate is shown to react with olefins in a CH 2 Cl 2 solution by three different pathways depending on structure and reaction conditions: (1) cationic cyclization, (2) C═C cleavage, and (3) allylic nitrosation. Possible reaction pathways are described.

Keyphrases

dna binding
high glucose
diabetic rats
room temperature
drug induced
electron transfer
endothelial cells
transcription factor