Visually Monitoring the Compactness of Polymer Matrixes Coded by Disparate Luminescence.

The intrinsic property disclosure of polymer systems by visual monitoring of photoluminescence behaviors is of great value in fundamental interest and promising applications. Three novel polymer films were obtained by simply doping methyl 9,14-diphenyl-9,14-dihydrodibenzo[a,c]phenazine-11-carboxylate (DPC) with three polymer materials. The photoluminescence behaviors of these films represented diverse fluorescence emissions from light orange to blue, especially room-temperature phosphorescence (RTP) emissions with ultralong lifetime, attributing to various configurations of DPC molecules provided by distinct microscopic environments in three polymer systems. The rigidity and regularity of polymer systems would be visually reflexed by luminescence regulation and temperature responses. In addition, irregular distribution of distinct polymer systems could be specifically monitored by both fluorescence and phosphorescence behaviors when doping different polymer materials into one blend film.