Accumulation, Characterization and Reactivity of Chiral Ammonium-Carboxonium Dications in Superacid.

Emanuela BerrinoThomas CantinMaxime ArtaultStefanie BeckChristoph JessenJérôme MarrotFrédéric Guegan Agnès Martin-MingotAndreas KornathSébastien Thibaudeau

Published in: Angewandte Chemie (International ed. in English) (2024)

The accumulation of chiral ammonium-oxocarbenium dications in superacid is evidenced by low-temperature NMR spectroscopy, X-ray diffraction analysis and confirmed by DFT calculations. Its potential for the diastereoselective remote hydrofunctionalization of non-activated alkene is also explored.

Keyphrases

ionic liquid
density functional theory
capillary electrophoresis
high resolution
molecular dynamics
molecular dynamics simulations
electron microscopy
molecular docking
mass spectrometry
magnetic resonance