An electrospray ionization mass spectrometry study of azidoacetic acid/transition metal complexes.

Vítor S PintoSusana C R MarquesPaula RodriguesM Teresa BarrosM Lourdes CostaG John LangleyM Tereza FernandezBenedito J C CabralM Filomena DuarteNarciso Couto

Published in: Rapid communications in mass spectrometry : RCM (2018)

MS/MS and HRMS experiments were able to elucidate azidoacetic acid complexation with Ni/Co/Fe and several gas-phase processes involving metal reduction and rearrangements. The definition of the coordination pattern dictated by the competition between the nitrogen and the oxygen atoms is also dependent on the metal centre in a very dynamic process. Copyright © 2017 John Wiley & Sons, Ltd.

Keyphrases

transition metal
mass spectrometry
ms ms
liquid chromatography
high resolution
metal organic framework
liquid chromatography tandem mass spectrometry
gas chromatography