Boosting Thermal Stability of Volatile Os Catalysts by Downsizing to Atomically Dispersed Species.

Os-based catalysts present remarkable catalytic activity; however, their use has been limited by the undesirable side reactions that generate highly toxic and volatile OsO 4 even at room temperature. Herein, we demonstrate that the thermal stability of Os-based catalysts can be dramatically improved by downsizing Os nanoparticles (NPs) into atomically dispersed species. We observed that Os NPs were converted into OsO 4 after calcination at 250 °C followed by sublimation, whereas single Os sites retained their structure after calcination. Temperature-programmed oxidation analysis confirmed that Os NPs started to undergo oxidation at 130 °C, whereas atomically dispersed Os preserved its state up to 300 °C. The CO oxidation activity of the atomically dispersed Os catalyst at 400 °C (100% conversion) was stably preserved over 30 h. By contrast, the activity of Os NP catalyst declined drastically. This study highlights the unique catalytic behavior of atomically dispersed catalysts, which is distinct from that of NP-based catalysts.