Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform.
Jordan F CorbeyBrian M RapkoZheming WangBruce K McNamaraRobert G SurbellaKristi L PellegriniJon M SchwantesPublished in: Inorganic chemistry (2018)
The crystal structures of americium species containing a common multifunctional phosphine oxide ligand, reported for its ability to extract f elements from acidic solutions, namely, 2,6-[Ph2P(O)CH2]2C5H3-NO, L, were finally determined after over three decades of separations studies involving these species and their surrogates. The molecular compounds Am(L)(NO3)3, Am 1:1, and [Am(L)2(NO3)][2(NO3)], Am 2:1, along with their neodymium and europium analogues, were synthesized and characterized using single-crystal X-ray crystallography, attenuated total reflectance Fourier transform infrared spectroscopy, and luminescence spectroscopy to provide a comprehensive comparison with new and known analogous complexes.
Keyphrases
- molecular docking
- high resolution
- ionic liquid
- single molecule
- drug delivery
- oxidative stress
- quantum dots
- cancer therapy
- solid state
- oxide nanoparticles
- magnetic resonance imaging
- case control
- computed tomography
- energy transfer
- single cell
- molecular dynamics simulations
- structure activity relationship
- light emitting
- electron microscopy
- crystal structure