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Tb3+, Eu3+ Co-doped CsPbBr3 QDs Glass with Highly Stable and Luminous Adjustable for White LEDs.

Yinzi ChengChenyang ShenLinli ShenWeidong XiangXiaojuan Liang
Published in: ACS applied materials & interfaces (2018)
Herein, we have introduced rare-earth cations Tb3+ and Eu3+ into CsPbBr3 QDs glass by conventional melt-quenching. Rare-earth cations like Tb3+ emit green light, causing the main peak of bromide lead cesium to exhibit some redshift, owing to the energy transfer between CsPbBr3 and Tb3+. To achieve adjustable light, Eu3+ emits red light, which was doped in this glass with different proportions to solve the problem of red deficiency. More importantly, Tb3+ and Eu3+ co-doped CsPbBr3 QDs glass shows a series of desirable characteristics due to the energy transfer between Tb3+ and Eu3+. Interestingly, the blue light radiated by blue chip can excite Tb3+, Eu3+, and CsPbBr3 perovskite effectively. We acquired high-performance white light-emitting diodes with color-rendering index, color coordinate transformation, and luminous efficiency of 85.7, 4945 K, and 63.21 lm/W under the current of 20 mA. This acquired Tb3+, Eu3+ co-doped CsPbBr3 QDs glass proved the significant feasibility of luminescent materials in solid warm light source.
Keyphrases
  • quantum dots
  • energy transfer
  • mycobacterium tuberculosis
  • metal organic framework
  • highly efficient
  • high throughput