Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy.

Yijue Xu Miriam Calabrese Nicola Demitri Andrea Pizzi Tamali Nag Ivan Hung Zhehong Gan Giuseppe Resnati David L Bryce

Published in: Chemical communications (Cambridge, England) (2023)

Matere bonds (MaB) to rhenium in a set of organic perrhenates are probed via 185/187 Re solid-state NMR in applied magnetic fields of up to 35.2 T, and via 185/187 Re NQR. 185/187 Re quadrupolar couplings distinguish between MaB samples and control samples, and their precise values are governed by shear strain of the ReO 4 - anions.

Keyphrases

transition metal
solid state
molecular dynamics simulations
monoclonal antibody
ionic liquid
molecularly imprinted
high resolution
single molecule