Temperature-driven order-disorder structural transition in the oxygen sub-lattice and the complex superstructure of the high-temperature polymorph of CaSrZn 2 Ga 2 O 7 .

Structural order-disorder plays a decisive role in the physical properties of materials, such as magnetism, second-order harmonic generation, and ionic conductivity, and it is thus widely utilized to manipulate the crystal structure and understand structure-property correlations. Herein, we report the structural polymorphism, complex crystal structure and temperature-driven irreversible order-disorder phase transition of the polar oxides (Sr 1- x Ca x )SrZn 2 Ga 2 O 7 . The low-temperature (LT) structure crystallizes in Pna 2 1 with partial Zn/Ga ordering. Upon heating, (Sr 1- x Ca x )SrZn 2 Ga 2 O 7 undergoes an irreversible phase transition from orthorhombic Pna 2 1 to hexagonal P 6 3 . Interestingly, the high-temperature (HT) P 6 3 structure possesses an unexpected 3/2-fold superstructure rather than a substructure of the low-temperature (LT) Pna 2 1 structure, which is a rare structural phenomenon in solid-state chemistry. This new HT superstructure is the most complex one in this series of oxides with 21 crystallographically independent sites determined accurately by a combination of the maximum entropy method and Rietveld refinement against high-resolution neutron powder diffraction data. In terms of the mechanism, this is a temperature-driven order-to-disorder transition in the oxygen sublattice. A careful structural analysis revealed that the oxygen disordering mainly occurs in the [SrO 3 ] layers of the HT structure and it can be understood as respective clockwise and anticlockwise rotations of distinct GaO 4 -tetrahedra along the c -axis. Alternating current electrochemical impedance spectroscopic analysis revealed that the oxygen disordering in the HT structure is incapable of giving rise to oxide ionic conductivity but does lead to increased electronic conduction compared to the LT structure. The optical properties of the CaSrZn 2 Ga 2 O 7 and Sr 2 Zn 2 Ga 2 O 7 representatives are also investigated in-depth via diffuse reflectance spectroscopy and theoretic calculations.