Adsorption of Polyelectrolyte onto Nanosilica Synthesized from Rice Husk: Characteristics, Mechanisms, and Application for Antibiotic Removal.

Adsorption of the polyelectrolyte polydiallyldimethylammonium chloride (PDADMAC) onto nanosilica (SiO₂) fabricated from rice husk was studied in this work. Nanosilica was characterized by X-ray diffraction, Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Adsorption of PDADMAC onto SiO₂ increased with increasing pH because the negative charge of SiO₂ is higher at high pH. Adsorption isotherms of PDADMAC onto silica at different KCl concentrations were fitted well by a two-step adsorption model. Adsorption mechanisms of PDADMAC onto SiO₂ are discussed on the basis of surface charge change, evaluation by ζ potential, surface modification by FTIR measurements, and the adsorption isotherm. The application of PDADMAC adsorption onto SiO₂ to remove amoxicillin antibiotic (AMX) was also studied. Experimental conditions such as contact time, pH, and adsorbent dosage for removal of AMX using SiO₂ modified with PDADMAC were systematically optimized and found to be 180 min, pH 10, and 10 mg/mL, respectively. The removal efficiency of AMX using PDADMAC-modified SiO₂ increased significantly from 19.1% to 92.3% under optimum adsorptive conditions. We indicate that PDADMAC-modified SiO₂ rice husk is a novel adsorbent for removal of antibiotics from aqueous solution.