Facile Synthesis of Boron and Nitrogen Dual-Doped Hollow Mesoporous Carbons for Efficient Reduction of 4-Nitrophenol.

The development of heteroatom-doped carbons with fascinating hierarchical porosity is of great significance for the improvement of catalytic properties of carbon catalysts. In this work, we report a boron and nitrogen codoped hollow mesoporous carbon (denoted as BN/HMC) via a simple synthesis route by direct pyrolysis of phenylboronic acid/melamine/ZIF-8 precursors. Thanks to their high specific surface area, unique hollow mesoporous nanoarchitecture, rich defects, and boron and nitrogen codoping, the obtained BN/HMC-0.05 can be employed as a high-efficiency carbon-based catalyst for the reduction of 4-nitrophenol. Theoretical calculations reveal that the B and N codoping in a carbon matrix are essential for the adsorption and activation of 4-nitrophenol. The present work might pave a new way in construction of metal-free carbon catalysts with both heteroatom doping and hierarchical porosity for various applications.