Highly-Ordered PdIn Intermetallic Nanostructures Obtained from Heterobimetallic Acetate Complex: Formation and Catalytic Properties in Diphenylacetylene Hydrogenation.

Formation of PdIn intermetallic nanoparticles supported on α-Al₂O₃ was investigated by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and hydrogen temperature-programmed desorption (H₂-TPD) methods. The metals were loaded as heterobimetallic Pd(μ-O₂CMe)₄In(O₂CMe) complex to ensure intimate contact between Pd and In. Reduction in H₂ at 200 °C resulted in Pd-rich PdIn alloy as evidenced by XRD and the disappearance of Pd hydride. A minor amount of Pd₁In₁ intermetallic phase appeared after reduction at 200 °C and its formation was accomplished at 400 °C. Neither monometallic Pd or in nor other intermetallic structures were found after reduction at 400⁻600 °C. Catalytic performance of Pd₁In₁/α-Al₂O₃ was studied in the selective liquid-phase diphenylacetylene (DPA) hydrogenation. It was found that the reaction rate of undesired alkene hydrogenation is strongly reduced on Pd₁In₁ nanoparticles enabling effective kinetic control of the hydrogenation, and the catalyst demonstrated excellent selectivity to alkene.