Unclonable Photonic Crystal Hydrogels with Controllable Encoding Capacity for Anticounterfeiting.

Inspired by the formation of random sparkling microcrystallines in naturally precious opals, we develop a new strategy to produce a class of unclonable photonic crystal hydrogels (UPCHs) induced by the electrostatic interaction effect, which further achieve unclonable encoding/decoding and random high-encrypted patterns along with an ultrahigh and controllable encoding capacity up to ca. 2 × 10 166055 . Owing to the randomness of colloidal crystals in the self-assembly process, UPCHs with randomly distributed sparkling spots are endowed with unpredictable/unrepeatable characteristics. This, coupled with the water response of UPCHs with angle dependence and robustness, can upgrade the encryption level and address some limitations of easy fading, limited durability, and high cost in practical uses of existing unclonable materials. Interestingly, UPCHs can be readily patterned to exhibit reliable and rapid authentication by utilizing artificial intelligence (AI) deep learning, which can find broad applications in developing unbreakable and portable information storage/steganography systems not limited to anticounterfeiting.