An investigation of palladium-catalyzed Stille-type cross-coupling of nitroarenes in perylenediimide series.
Aline MakhloutahDanylo HatychThomas ChartierLou RocardAntoine GoujonFrançois-Xavier FelpinPiétrick HudhommePublished in: Organic & biomolecular chemistry (2022)
We report herein an unprecedented palladium-catalyzed cross-coupling reaction between mononitro-perylenediimide (PDI) and various arylstannanes. Optimized conditions developed with this Stille-type reaction allow the grafting of (hetero)aryls of various electronic nature in the bay region of PDIs. Moreover, we capitalized on the high selectivity of this cross-coupling through the desymmetrization of the dinitro-PDI substrate.
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