Unlocking Molecular Secrets in a Monomer-Assembly-Promoted Zn-Metalated Catalytic Porous Organic Polymer for Light-Responsive CO 2 Insertion.

Anthropogenic carbon dioxide (CO 2 ) emission is soaring day by day due to fossil fuel combustion to fulfill the daily energy requirements of our society. The CO 2 concentration should be stabilized to evade the deadly consequences of it, as climate change is one of the major consequences of greenhouse gas emission. Chemical fixation of CO 2 to other value-added chemicals requires high energy due to its stability at the highest oxidation state, creating a tremendous challenge to the scientific community to fix CO 2 and prevent global warming caused by it. In this work, we have introduced a novel monomer-assembly-directed strategy to design va isible-light-responsive conjugated Zn-metalated porous organic polymer ( Zn@MA-POP ) with a dynamic covalent acyl hydrazone linkage, via a one-pot condensation between the self-assembled monomer 1,3,5-benzenetricarbohydrazide ( TPH ) and a Zn complex ( Zn@COM ). We have successfully explored as-synthesized Zn@MA-POP as a potential photocatalyst in visible-light-driven CO 2 photofixation with styrene epoxide ( SE ) to styrene carbonate ( SC ). Nearly 90% desired product ( SC ) selectivity has been achieved with our Zn@MA-POP , which is significantly better than that for the conventional Zn@TiO 2 (∼29%) and Zn@gC 3 N 4 (∼26%) photocatalytic systems. The excellent light-harvesting nature with longer lifetime minimizes the radiative recombination rate of photoexcited electrons as a result of extended π-conjugation in Zn@MA-POP and increased CO 2 uptake, eventually boosting the photocatalytic activity. Local structural results from a first-shell EXAFS analysis reveals the existence of a Zn(N 2 O 4 ) core structure in Zn@MA-POP , which plays a pivotal role in activating the epoxide ring as well as capturing the CO 2 molecules. An in-depth study of the POP-CO 2 interaction via a density functional theory (DFT) analysis reveals two feasible interactions, Zn@MA-POP-CO 2 -A and Zn@MA-POP-CO 2 -B , of which the latter has a lower relative energy of 0.90 kcal/mol in comparison to the former. A density of states (DOS) calculation demonstrates the lowering of the LUMO energy (EL) of Zn@MA-POP by 0.35 and 0.42 eV, respectively, for the two feasible interactions, in comparison to Zn@COM . Moreover, the potential energy profile also unveils the spontaneous and exergonic photoconversion pathways for the SE to SC conversion. Our contribution is expected to spur further interest in the precise design of visible-light-active conjugated porous organic polymers for CO 2 photofixation to value-added chemicals.