A π-extended β-diketiminate ligand via a templated Scholl approach.

Published in: Chemical communications (Cambridge, England) (2024)

We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[ f , g ]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.

Keyphrases

electron transfer
molecularly imprinted
gold nanoparticles
hydrogen peroxide
nitric oxide
mass spectrometry
high resolution
case control
solar cells