Switching of Reaction Pathway from C-C Rollover to C-N Ring-Extension Annulation.

This work discloses that a simple change in the anion of a copper(II) reagent along with the reaction solvent can dramatically alter the course of a Cp*RhIII -catalyzed C-H activation-annulation reaction leading to completely switchable chemoselective products. The nature of the anion in terms of its coordinating ability and basicity, and also the polarity of the solvent have been found to be the crucial factors in the observed divergence.