Microwave induced "egg yolk" structure in Cr/V-MIL-53.

Hannes DepauwIrena NevjestićJonatan De WinneGuangbo WangKatrien HaustraeteKaren LeusAn VerberckmoesChristophe DetavernierFreddy CallensEls De CanckHenk Vrielinck Pascal Van Der Voort

Published in: Chemical communications (Cambridge, England) (2018)

Using a one pot microwave procedure, mixed-metal "egg yolk" MOFs are created, with a core of (Cr/V)-MIL-53 and a shell of Cr-MIL-53. In contrast, the solvothermal method produces homogeneous mixed-metal MOFs. The influence of Cr and V on the flexibility and breathing was studied via T-XRPD and CO2 adsorption measurements.

Keyphrases

metal organic framework
solid phase extraction
magnetic resonance
high glucose
mass spectrometry
drug induced
oxidative stress
simultaneous determination