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In Situ Phosphorization for Constructing Ni 5 P 2 -Ni Heterostructure Derived from Bimetallic MOF for Li-S Batteries.

Meng DuPengbiao GengWanchang FengHaoyang XuBing LiHuan Pang
Published in: Small (Weinheim an der Bergstrasse, Germany) (2024)
Heterostructured materials commonly consist of bifunctions due to the different ingredients. For host material in the sulfur cathode of lithium-sulfur (Li-S) batteries, the chemical adsorption and catalytic activity for lithium polysulfides (LiPS) are important. This work obtains a Ni 5 P 2 -Ni nanoparticle (Ni 5 P 2 -NiNPs) heterostructure through a confined self-reduction method followed by an in situ phosphorization process using Al/Ni-MOF as precursors. The Ni 5 P 2 -Ni heterostructure not only has strong chemical adsorption, but also can effectively catalyze LiPS conversion. Furthermore, the synthetic route can keep Ni 5 P 2 -NiNPs inside of the nanocomposites, which have structural stability, high conductivity, and efficient adsorption/catalysis in LiPS conversion. These advantages make the assembled Li-S battery deliver a reversible specific capacity of 619.7 mAh g - 1 at 0.5 C after 200 cycles. The in situ ultraviolet-visible technique proves the catalytic effect of Ni 5 P 2 -Ni heterostructure on LiPS conversion during the discharge process.
Keyphrases
  • metal organic framework
  • transition metal
  • solid state
  • gold nanoparticles
  • ion batteries
  • crystal structure