Multiscale Evolution of Bulk Heterojunction Solar Cell Active Layers under Thermal Stress.

A multimodality spectromicroscopy imaging system has been developed to offer the essential capability of in situ characterization of functional materials at multiple length scales during the morphology evolution and phase development under external stimuli. The photoactive layer of bulk heterojunction solar cell, whose performance is strongly correlated to the structural features over a wide range of length scales, was characterized under thermal stress. Three stages of thermotropic evolution were monitored continuously by the spectromicroscopy imaging system to reveal the critical information from the molecular level to meso- and microscale. The optimized thermal annealing temperature window and preferred temperature dropping operation were identified to promote the performance of the photoactive layer.