Diagonal and Vertical B ← N Lewis Pair Functionalized Perylenes.

Yufeng ZhangZhenyi ZhangLei JiWei Huang

Published in: Organic letters (2023)

Two novel multiple B ← N Lewis pair functionalized perylenes are reported. While OBN-Pery shows a centrosymmetric and planar architecture, PBN-Pery displays an axisymmetric and twist structure. B ← N functionalization in both of them results in a large decrease in the HOMO-LUMO energy gap. PBN-Pery in particular has a low LUMO energy level (-3.00 eV) and red emission at the NIR I region with high fluorescence quantum yield.

Keyphrases

quantum dots
energy transfer
molecularly imprinted
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molecular dynamics
single molecule
fluorescence imaging
solid phase extraction