Iron homo- and heterobimetallic complexes supported by a symmetrical dinucleating ligand.

Pablo Ríos Matthew S See Oscar Gonzalez Rex C Handford Amélie Nicolay Guodong Rao R David Britt D Kwabena Bediako T Don Tilley

Published in: Chemical communications (Cambridge, England) (2024)

The selective synthesis of biomimetic Fe/Mn complexes able to mimic the geometry and catalytic activity of enzymes possessing this cofactor is still a challenge. Herein, we discuss the stepwise synthesis, characterization, and magnetic properties of a Fe(II)/Mn(II) species and related Fe(II)/Fe(II) complexes.

Keyphrases

metal organic framework
mass spectrometry