Optical Control of Crossing the Conical Intersection in β-Carotene.

Optical control of dynamic processes has been challenging yet has only been demonstrated in several chemical and biological systems. The control of a reaction passing the widely present conical intersection has not been realized. Here, we modulated the phase of the excitation pulse to control the dynamics of β-carotene through accessing the conical intersection (CI). We observed different dynamics in 110-220 fs into the CI and the consecutive process in 400-600 fs through another CI by various chirped excitation pulses. We successfully controlled those ultrafast wavepacket dynamics passing the CIs on the femtosecond time scales. The method developed here can be used to control a various of ultrafast chemical and biological reactions through the CI(s).