Fluorinated Aliphatic Diazirines: Preparation, Characterization, and Model Photolabeling Studies.
Yurii KorniiOleg ShablykinTaras TarasiukOleksandr StepaniukVitaliy MatvienkoDanylo AloshynNataliia ZahorodniukIryna V SadkovaPavel K MykhailiukPublished in: The Journal of organic chemistry (2022)
The previously unknown difluoromethyl diazirines and the previously neglected trifluoromethyl-aliphatic diazirines were synthesized and characterized. Model photolabeling experiments and biological studies showed that these compounds could indeed be used as photoaffinity labels.