Route to tunable room temperature electric polarization in SrTiO3-CoFe2O4 heterostructures.
Laura MaurelJavier Herrero-MartinFederico MottiHari Babu VasiliCinthia PiamontezeLaura J HeydermanValerio ScagnoliPublished in: Journal of materials chemistry. C (2021)
Utilizing the magnetostrictive properties of CoFe2O4, we demonstrate reversible room temperature control of the Ti electronic structure in SrTiO3-CoFe2O4 heterostructures, by inducing local and reversible strain in the SrTiO3. By means of X-ray absorption spectroscopy, we have ascertained the changes that take place in the energy levels of the Ti 3d orbitals under the influence of an external magnetic field. The observed Ti electronic state when the sample is subjected to moderately large external magnetic fields and the disappearance of the induced phase upon their removal indicates lattice distortions that are suggestive of the development of a net electric polarization.