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Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications.

Aiswarya Abhisek MohapatraWaleed Kuar YualYadong ZhangAnton Aleksandrovich SamoylovJonathan ThurstonCasey M DavisDeclan P McCarthyAdam D PrintzMichael F ToneyErin L RatcliffNeal R ArmstrongAnn L GreenawayStephen BarlowSeth R Marder
Published in: Chemical communications (Cambridge, England) (2024)
Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.
Keyphrases
  • ionic liquid
  • gold nanoparticles
  • molecularly imprinted
  • electron transfer
  • label free
  • oxide nanoparticles
  • simultaneous determination