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Redox-Annulations of Cyclic Amines with Electron-Deficient o-Tolualdehydes.

Anirudra PaulAlafate AdiliDaniel Seidel
Published in: Organic letters (2019)
Amines such as 1,2,3,4-tetrahydroisoquinoline undergo redox-neutral annulations with 2-methyl-3,5-dinitrobenzaldehyde and closely related substrates. Acetic acid serves as the solvent and sole promoter of these transformations which involve dual C-H functionalization.
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