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Multiresponsive Behavior of Functional Poly(p-phenylene vinylene)s in Water.

Kanykei RyskulovaAnupama Rao Gulur SrinivasThomas Kerr-PhillipsHui PengDavid BarkerJadranka Travas-SejdicRichard Hoogenboom
Published in: Polymers (2016)
The multiresponsive behavior of functionalized water-soluble conjugated polymers (CPs) is presented with potential applications for sensors. In this study, we investigated the aqueous solubility behavior of water-soluble CPs with high photoluminescence and with a particular focus on their pH and temperature responsiveness. For this purpose, two poly(phenylene vinylene)s (PPVs)-namely 2,5-substituted PPVs bearing both carboxylic acid and methoxyoligoethylene glycol units-were investigated, with different amount of carboxylic acid units. Changes in the pH and temperature of polymer solutions led to a response in the fluorescence intensity in a pH range from 3 to 10 and for temperatures ranging from 10 to 85 °C. Additionally, it is demonstrated that the polymer with the largest number of carboxylic acid groups displays upper critical solution temperature (UCST)-like thermoresponsive behavior in the presence of a divalent ion like Ca2+. The sensing capability of these water-soluble PPVs could be utilized to design smart materials with multiresponsive behavior in biomedicine and soft materials.
Keyphrases
  • water soluble
  • quantum dots
  • photodynamic therapy
  • single molecule
  • mass spectrometry
  • ionic liquid
  • energy transfer
  • low cost
  • simultaneous determination