Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins.

Chihiro MaedaKanae OgawaKosuke SadanagaKazuto Takaishi Tadashi Ema

Published in: Chemical communications (Cambridge, England) (2019)

Doubly (R)-binaphthyl-strapped porphyrins with methylene chains were synthesized. The CD spectra showed the positive Cotton effect around the Soret bands, and several porphyrins showed CPL. In addition, we found that the chiral porphyrins were applicable to kinetic resolution of epoxide with CO2.

Keyphrases

ionic liquid
capillary electrophoresis
single molecule
mass spectrometry
molecular dynamics
nk cells
crystal structure