Calcium stannyl formation by organostannane dehydrogenation.

Louis J MorrisMichael S HillIan MannersClaire L McMullinMary F MahonNasir A Rajabi

Published in: Chemical communications (Cambridge, England) (2019)

Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.

Keyphrases

protein kinase
molecular docking
ionic liquid
molecular dynamics simulations
electron transfer