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Synthesis, Regioselective Bromination, and Functionalization of Coronene Tetracarboxydiimide.

Taifeng LiuYongchao GeBaolai SunBrandon FowlerHexing LiColin P NuckollsShengxiong Xiao
Published in: The Journal of organic chemistry (2019)
A new method for the effective synthesis of coronene tetracarboxydiimide (CDI) was developed by utilizing inexpensive and nontoxic potassium vinyltrifluoroborate. Controllable brominations of CDI were accomplished to yield CDI mono-, di-, tri-, and tetra-bromides, which could be used as synthon and functionalized by aromatic nucleophilic substitution and the Sonogashira coupling reaction.
Keyphrases
  • quantum dots
  • biofilm formation
  • amino acid
  • staphylococcus aureus
  • electron transfer