Determination of Carbamates and Thiocarbamates in Water, Soil and Sediment of the Formoso River, TO, Brazil.
Patricia Martins GuardaAntonina M S PontesRaquel de S DomicianoLarissa da S GualbertoDanylo B MendesEmerson A GuardaJosé E C da SilvaPublished in: Chemistry & biodiversity (2020)
Considering the increase in agricultural production in Brazil, the use of pesticides for this production, and that there are no studies on pesticides in the region, the presence of carbamates and thiocarbamates was investigated in different environmental compartments of the Formoso River, TO, Brazil, by UHPLC/MS/MS. The collections were made on the banks of this river, in the area of influence of the agricultural project. The active principles were not found in the soil and sediment samples, only the propoxur principle was found in the water, reaching values of up to 0.025 μg L-1 . It was found that the biodiversity of the Tocantinense savannah is under threat, because even though only one of the substances surveyed, propoxur and its derivatives, has been detected, they are substances of high toxicity and tendency to contaminate surface and groundwater to varying degrees and irreversible damage to different species.
Keyphrases
- heavy metals
- risk assessment
- ms ms
- human health
- water quality
- drinking water
- health risk assessment
- health risk
- oxidative stress
- climate change
- solid phase extraction
- gas chromatography
- quality improvement
- polycyclic aromatic hydrocarbons
- liquid chromatography tandem mass spectrometry
- organic matter
- simultaneous determination
- plant growth
- atomic force microscopy
- high resolution mass spectrometry
- high resolution
- high speed