2D Bismuthene Metal Electron Mediator Engineering Super Interfacial Charge Transfer for Efficient Photocatalytic Reduction of Carbon Dioxide.

The interfacial charge transfer still limits the photoactivity of artificial Z-scheme photocatalysts although they showed complementary light absorption and a strong photoredox ability. In this study, layered metallene is designed as an efficient electron mediator for constructing a C3N4/bismuthene/BiOCl 2D/2D/2D Z-scheme system. This bismuthene serves as a bridge processing superior charge conductibility, abundant metal-semiconductor contact sites, and the shortened charge diffusion distance, enhancing the photocatalytic CO2 reduction reaction activity and stability. Density functional theory calculations show that the bismuthene creates a built-in electric field and congregates interfacial electrons, which is confirmed by the stable and consistent emission of the ultrafast transient absorption spectra. This work gives new insight into the interface design of Z-scheme photocatalysts by selecting a novel metallene electron mediator.