Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes.
Pei-Zhi ZhangLing ZhangJian-An LiAdedamola ShoberuJian-Ping ZouWei ZhangPublished in: Organic letters (2017)
A double-functionalization reaction of alkenes through Mn(OAc)3-mediated phosphinoyl radical addition followed by CuCN-catalyzed cyanation is introduced. This one-pot reaction is performed under mild conditions to afford vicinal cyanophosphinoylation products.
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